By R. Morris Bullock
Written for chemists in and academia, this prepared reference and guide summarizes contemporary development within the improvement of latest catalysts that don't require beneficial metals. The examine therefore provided issues the right way to how new catalysts may possibly finally supplant using important metals in a few different types of reactions, whereas highlighting the rest challenges.
a necessary copanion for natural and catalytic chemists, in addition to these operating with/on organometallics and graduate students.
From the contents:
* Catalysis regarding the H' move Reactions of First-Row Transition Metals
* Catalytic aid of Dinitrogen to Ammonia through Molybdenum Complexes
* Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis
* Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions
* Olefin Oligomerizations and Polymerizations Catalyzed by way of Iron and Cobalt Complexes
* Cobalt and Nickel Catalyzed Reactions concerning C-H and C-N Activation Reactions
* improvement of Molecular Electrocatalysts for H2 Oxidation and creation in accordance with reasonably cheap Metals
* Nickel-Catalyzed Reductinve Couplings and Cyclizations
* Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions
* Copper-Catalyzed Azide-Alkyne Cycloaddition
* "Frustrated Lewis Pairs": A Metal-Free approach for Hydrogenation Catalysis
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Additional info for Catalysis without Precious Metals
114, 3123–3125. V. (1998) J. Am. Chem. , 120, 8007–8008. , and Murai, S. (1998) Bull. Chem. Soc. , 71, 285–298. J. (2004) J. Am. Chem. , 126, 7875–7880. F. (2010) Organotransition Metal Chemistry: From Banding to Catalysis. University Science Books, Sausalito, USA, pp. 122–136. 25 2 Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Richard R. 1 Introduction In the 1960s it was ﬁrst recognized that dinitrogen is reduced to ammonia in the environment by a metalloenzyme, an FeMo nitrogenase [1–5].
And Hirose, H. (1968) Bull. Chem. Soc. , 41, 2815. O. (1992) J. Am. Chem. , 114, 3123–3125. V. (1998) J. Am. Chem. , 120, 8007–8008. , and Murai, S. (1998) Bull. Chem. Soc. , 71, 285–298. J. (2004) J. Am. Chem. , 126, 7875–7880. F. (2010) Organotransition Metal Chemistry: From Banding to Catalysis. University Science Books, Sausalito, USA, pp. 122–136. 25 2 Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Richard R. 1 Introduction In the 1960s it was ﬁrst recognized that dinitrogen is reduced to ammonia in the environment by a metalloenzyme, an FeMo nitrogenase [1–5].
63 V, CrCp*2 is a viable reductant of Mo(NH3)+. 7 kcal mol−1 below the S = 3/2 state ; high spin Mo(NH3) therefore is unlikely to be relevant in the chemistry of Mo(NH3). 13). 13) 37 38 2 Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Mo(NH3) was prepared by treating MoN2 with ammonia (∼4 equiv) in C6D6 solution in the absence of dinitrogen for 16 h at 22 °C. 06 Å). These (small) changes in bond distances are consistent with an electron being added to a dxz or dyz orbital on Mo, although it is not clear why the Mo–NH3 bond shortens upon reduction of Mo(NH3)+ to Mo(NH3).